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Intramolecular charge transfer and dual fluorescence of 4-(dimethylamino)benzonitrile: ultrafast branching followed by a two-fold decay mechanism

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a
Interdisziplinäres Zentrum für Molekulare Materialien (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg Staudtstrasse 7/B2, D-91058 Erlangen, Germany
E-mail: pedro.brana-coto@physik.uni-erlangen.de
b
Instituto de Ciencia Molecular (ICMOL), Universitat de València, P. O. Box 22085, Valencia, Spain
c
Laboratoire Francis Perrin, CEA/DSM/DRECAM/SPAM-CNRS URA 2453 CEA/Saclay, 91 191 Gif-sur-Yvette, France
E-mail: thomas.gustavsson@cea.fr
d
Department of Physics, The Ohio State University, Columbus, USA
E-mail: fujiwara@physics.osu.edu
e
Department of Chemistry and The Center for Laser and Optical Spectroscopy, The University of Akron, Akron, USA
E-mail: elim@uakron.edu
Phys. Chem. Chem. Phys., 2011,13, 15182-15188

DOI: 10.1039/C1CP21089K
Received 07 Apr 2011, Accepted 21 Jun 2011
First published online 18 Jul 2011
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