Issue 9, 2011

Saturation factor of nitroxide radicals in liquid DNP by pulsed ELDOR experiments

Abstract

We propose the use of the pulse electron double resonance (ELDOR) method to determine the effective saturation factor of nitroxide radicals for dynamic nuclear polarization (DNP) experiments in liquids. The obtained values for the nitroxide radical TEMPONE-D,15N at different concentrations are rationalized in terms of spin relaxation and are shown to fulfil the Overhauser theory.

Graphical abstract: Saturation factor of nitroxide radicals in liquid DNP by pulsed ELDOR experiments

Article information

Article type
Communication
Submitted
12 Oct 2010
Accepted
04 Jan 2011
First published
24 Jan 2011

Phys. Chem. Chem. Phys., 2011,13, 3630-3633

Saturation factor of nitroxide radicals in liquid DNP by pulsed ELDOR experiments

M. Türke and M. Bennati, Phys. Chem. Chem. Phys., 2011, 13, 3630 DOI: 10.1039/C0CP02126A

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