Issue 22, 2010

High power pulsed dynamic nuclear polarisation at 94 GHz

Abstract

In this communication we report initial results using high power pulsed techniques at 94 GHz to perform solid state Dynamic Nuclear Polarisation (DNP) on high volume samples. It is shown that excitation with short pulses, comparable to the π/2 pulse length, at fast repetition rates can result in higher DNP enhancements relative to continuous wave (cw) excitation for the same average power. Peak enhancements are observed at an average power of only a few hundred mW delivered to the sample.

Graphical abstract: High power pulsed dynamic nuclear polarisation at 94 GHz

Article information

Article type
Communication
Submitted
02 Feb 2010
Accepted
14 Apr 2010
First published
28 Apr 2010

Phys. Chem. Chem. Phys., 2010,12, 5752-5756

High power pulsed dynamic nuclear polarisation at 94 GHz

R. I. Hunter, P. A. S. Cruickshank, D. R. Bolton, P. C. Riedi and G. M. Smith, Phys. Chem. Chem. Phys., 2010, 12, 5752 DOI: 10.1039/C002251A

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