Ligand-oriented assembly of a porous metal–organic framework by [CuI4I4] clusters and paddle-wheel [CuII2(COO)4(H2O)2] subunits

Guoming Wang; Zhenzhen Xue; Jie Pan; Li Wei; Songde Han; Jinjie Qian; Zonghua Wang

doi:10.1039/C6CE01954D

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Ligand-oriented assembly of a porous metal–organic framework by [Cu^I₄I₄] clusters and paddle-wheel [Cu^II₂(COO)₄(H₂O)₂] subunits†

Guoming Wang,*^a Zhenzhen Xue,^a Jie Pan,^a Li Wei,^a Songde Han,^a Jinjie Qian

^b and Zonghua Wang^a

Author affiliations

* Corresponding authors

^a College of Chemistry and Chemical Engineering, Collaborative Innovation Center for Marine Biomass Fiber Materials and Textiles, Qingdao University, Shandong 266071, PR China
E-mail: gmwang_pub@163.com

^b College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, PR China

Abstract

A novel porous mixed-valence copper–organic framework based on Cu^I₄I₄ clusters and paddle-wheel [Cu^II₂(COO)₄(H₂O)₂] moieties was synthesized through a ligand-oriented assembly. The mixed-valence Cu(I)–Cu(II) complex features the coexistence of micro-sized cages and 1D channels and its sorption behaviour has been investigated.

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Article information

DOI: https://doi.org/10.1039/C6CE01954D
Article type: Communication
Submitted: 08 Sep 2016
Accepted: 23 Sep 2016
First published: 23 Sep 2016

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CrystEngComm, 2016,18, 8362-8365

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Ligand-oriented assembly of a porous metal–organic framework by [Cu^I₄I₄] clusters and paddle-wheel [Cu^II₂(COO)₄(H₂O)₂] subunits

G. Wang, Z. Xue, J. Pan, L. Wei, S. Han, J. Qian and Z. Wang, CrystEngComm, 2016, 18, 8362 DOI: 10.1039/C6CE01954D

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