Issue 45, 2016
From the journal:

CrystEngComm

Self-assembly and photocatalytic properties of Ta/W mixed-addendum polyoxometalate and transition-metal cations†

Peng Huang,a   Xi-Guang Han,a   Xiu-Ling Li,a   Chao Qin,*b   Xin-Long Wangb  and  Zhong-Min Su*b  

* Corresponding authors

a Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials, Department of Chemistry, School of Chemistry and Chemical Engineering, Jiangsu Normal University, Xuzhou, PR China

b National & Local United Engineering Lab for Power Battery, Northeast Normal University, Changchun, 130024 Jilin, PR China
E-mail: qinc703@nenu.edu.cn, zmsu@nenu.edu.cn

Abstract

Two nanoscale Ta/W mixed-addendum polyoxometalates, Cs5K2[(Si2W18Ta6O78)Cr(H2O)4]·8H2O and Cs3K4H2[(Si2W18Ta6O78)FeCl2(H2O)2]·15H2O involving [SiTa3W9O40]7− fundamental building units, have been synthesized, both of which show photocatalytic hydrogen evolution activity.

Graphical abstract: Self-assembly and photocatalytic properties of Ta/W mixed-addendum polyoxometalate and transition-metal cations

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Article information

DOI
https://doi.org/10.1039/C6CE01953F
Article type
Communication
Submitted
08 Sep 2016
Accepted
19 Oct 2016
First published
25 Oct 2016

CrystEngComm, 2016,18, 8722-8725

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Self-assembly and photocatalytic properties of Ta/W mixed-addendum polyoxometalate and transition-metal cations

P. Huang, X. Han, X. Li, C. Qin, X. Wang and Z. Su, CrystEngComm, 2016, 18, 8722 DOI: 10.1039/C6CE01953F

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