Issue 23, 2016

Anion-templated 2D frameworks from hexahydroxytriphenylene

Abstract

Hexahydroxytriphenylene (HHTP) forms 2D frameworks through O–H⋯anion hydrogen bonds with a range of anions. In all cases, 1 : 1 co-crystals of HHTP and tetraalkylammonium·anion salts are obtained, which have a layered 2D structure. When HSO4 was used as anion, an unprecedented methylation reaction was observed giving crystals containing the methylsulfate anion (MeOSO3).

Graphical abstract: Anion-templated 2D frameworks from hexahydroxytriphenylene

Supplementary files

Article information

Article type
Communication
Submitted
03 Feb 2016
Accepted
27 Mar 2016
First published
06 Apr 2016
This article is Open Access
Creative Commons BY-NC license

CrystEngComm, 2016,18, 4281-4284

Anion-templated 2D frameworks from hexahydroxytriphenylene

M. Morshedi, A. C. Willis and N. G. White, CrystEngComm, 2016, 18, 4281 DOI: 10.1039/C6CE00297H

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements