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Issue 6, 2015
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Interpenetrated and non-interpenetrated homochiral metal–organic frameworks based on (R)-2,2′-dihydroxy-1,1′-binaphthyl-5,5′-dibenzoic acid

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Abstract

A new example of interpenetration that is simply controlled by modifying hydroxyl function in homochiral MOFs is reported. Interpenetrated and non-interpenetrated chiral metal–organic frameworks (MOF-1 and MOF-2) were prepared by solvothermal reactions of [Cu(NO3)2]·3H2O in N,N-dimethylformamide (DMF)–H2O solution with (R)-2,2′-dihydroxy-1,1′-binaphthyl-5,5′-dibenzoic acid (H2L1) and (R)-2,2′-dimethoxy-1,1′-binaphthyl-5,5′-dibenzoic acid (H2L2), respectively. Interpenetrated chiral MOF-1 exhibited much higher catalytic performance in the Diels–Alder reaction of acrolein and 1,3-cyclohexadiene than non-interpenetrated chiral MOF-2.

Graphical abstract: Interpenetrated and non-interpenetrated homochiral metal–organic frameworks based on (R)-2,2′-dihydroxy-1,1′-binaphthyl-5,5′-dibenzoic acid

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Publication details

The article was received on 07 Nov 2014, accepted on 06 Dec 2014 and first published on 09 Dec 2014


Article type: Paper
DOI: 10.1039/C4CE02210F
Citation: CrystEngComm, 2015,17, 1291-1295
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    Interpenetrated and non-interpenetrated homochiral metal–organic frameworks based on (R)-2,2′-dihydroxy-1,1′-binaphthyl-5,5′-dibenzoic acid

    K. Tanaka, D. Yanamoto, K. Yoshimura, T. Anami and Z. Urbanczyk-Lipkowska, CrystEngComm, 2015, 17, 1291
    DOI: 10.1039/C4CE02210F

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