A novel chlorine-containing borophosphate based on (4,3)-connected 3-D borophosphate anion [B6P11O42(OH)2]13− with unique B : P ratio and 22-tetrahedral cages

Yuquan Feng; Min Li; Hengzhen Shi; Qunzeng Huang; Dongfang Qiu

doi:10.1039/C3CE26918C

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A novel chlorine-containing borophosphate based on (4,3)-connected 3-D borophosphate anion [B₆P₁₁O₄₂(OH)₂]¹³⁻ with unique B : P ratio and 22-tetrahedral cages†

Yuquan Feng,^a Min Li,^b Hengzhen Shi,*^a Qunzeng Huang^a and Dongfang Qiu^a

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* Corresponding authors

^a College of Chemistry and Pharmacy Engineering, Nanyang Normal University, Nanyang 473061, China
E-mail: hzshi@nynu.edu.cn
Fax: +86 377 6351 2517
Tel: +86 377 6351 3769

^b Department of Chemistry, Henan Institute of Education, Zhengzhou 450046, China
E-mail: 0811jyxy@163.com
Fax: +86 371 6930 3678
Tel: +86 371 6930 3678

Abstract

A novel chlorine-containing borophosphate Na₁₃(H₃O)₂ [B₆P₁₁O₄₂(OH)₂]Cl₂·H₂O has been hydrothermally synthesized and structurally characterized. The compound not only possesses a unique B : P ratio of 6 : 11, but also displays a novel (4,3)-connected three-dimensional borophosphate anionic partial structure containing 22-tetrahedral cages.

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Article information

DOI: https://doi.org/10.1039/C3CE26918C
Article type: Communication
Submitted: 25 Nov 2012
Accepted: 16 Jan 2013
First published: 16 Jan 2013

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CrystEngComm, 2013,15, 2048-2051

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A novel chlorine-containing borophosphate based on (4,3)-connected 3-D borophosphate anion [B₆P₁₁O₄₂(OH)₂]¹³⁻ with unique B : P ratio and 22-tetrahedral cages

Y. Feng, M. Li, H. Shi, Q. Huang and D. Qiu, CrystEngComm, 2013, 15, 2048 DOI: 10.1039/C3CE26918C

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