Issue 7, 2013

Engineering of a polar crystal structure exclusively by π–π stacking between aryl and polyfluoroaryl groups

Abstract

1-(4-Nitrilo-2,3,5,6-tetrafluorophenyl)benzimidazole crystallizes in the polar space group Cc. The structure arises from the geometry of the molecule which gives columns of π–π stacked nitrilotetrafluorophenyl and benzimidazole groups in two almost orthogonal directions.

Graphical abstract: Engineering of a polar crystal structure exclusively by π–π stacking between aryl and polyfluoroaryl groups

Supplementary files

Additions and corrections

Article information

Article type
Communication
Submitted
02 Nov 2012
Accepted
05 Dec 2012
First published
05 Dec 2012

CrystEngComm, 2013,15, 1293-1295

Engineering of a polar crystal structure exclusively by π–π stacking between aryl and polyfluoroaryl groups

J. R. Lane, G. C. Saunders and S. J. Webb, CrystEngComm, 2013, 15, 1293 DOI: 10.1039/C2CE26796A

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