Issue 2, 2013
From the journal:

CrystEngComm

Hydrothermal synthesis of benzothiazole–carboxylic cadmium(ii) coordination networks: pH-controlled topologies and compositional distributions†

Hai-Yang Yu,a   Xin Fang,*a   Ke-Ke Zhang,a   Mei-Jin Lin,*a   Dan Gao,a   Ming-Dong Huangab  and  Jun-Dong Wanga  

* Corresponding authors

a College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian, 350108, P. R. China
E-mail: fangxin@fzu.edu.cn, mei-jin_lin@fzu.edu.cn

b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, P. R. China

Abstract

Using the hydrothermal synthetic method, two cadmium complexes (1 and 2) with an identical chemical formula of [Cd(ABTC)2]n (ABTC = 2-aminobenzothiazole-6-carboxylic acid) but completely different topologies were prepared at two different pH values of reaction solution, 5.3 and 7.3, respectively. Reaction with a pH in between resulted in a mixture of 1 and 2, and the ratio of two products was proportional to pH value of the reaction condition.

Graphical abstract: Hydrothermal synthesis of benzothiazole–carboxylic cadmium(ii) coordination networks: pH-controlled topologies and compositional distributions

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Article information

DOI
https://doi.org/10.1039/C2CE26559A
Article type
Paper
Submitted
13 Mar 2012
Accepted
29 Oct 2012
First published
31 Oct 2012

CrystEngComm, 2013,15, 343-348

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Hydrothermal synthesis of benzothiazole–carboxylic cadmium(II) coordination networks: pH-controlled topologies and compositional distributions

H. Yu, X. Fang, K. Zhang, M. Lin, D. Gao, M. Huang and J. Wang, CrystEngComm, 2013, 15, 343 DOI: 10.1039/C2CE26559A

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