Ti[BP2O7(OH)3]: The first titanium borophosphate containing novel anionic partial structure

Hengzhen Shi; Yuquan Feng; Qunzeng Huang; Dongfang Qiu; Min Li; Kecheng Liu

doi:10.1039/C1CE06233F

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Ti[BP₂O₇(OH)₃]: The first titanium borophosphate containing novel anionic partial structure†

Hengzhen Shi,*^a Yuquan Feng,^a Qunzeng Huang,^a Dongfang Qiu,^a Min Li^b and Kecheng Liu^a

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* Corresponding authors

^a College of Chemistry and Pharmacy Engineering, Nanyang Normal University, Nanyang, China
E-mail: hzshi@nynu.edu.cn
Fax: +86 377 6351 2517
Tel: +86 377 6351 3769

^b Department of Chemistry, Henan Institute of Education, Zhengzhou, China
E-mail: 0811jyxy@163.com
Fax: +86 371 6930 3678
Tel: + 86 371 6930 3678

Abstract

The first titanium borophosphate Ti[BP₂O₇(OH)₃] has been hydrothermally synthesized and structurally characterized. The compound has a three-dimensional open-framework architecture by linking TiO₆ octahedra to the anionic layers [BP₂O₇(OH)₃]⁴⁻ which are built up from BO₃(OH) tetrahedra and PO₃(OH) tetrahedra. The compound not only represents the first transition metal titanium(IV) borophosphate but also displays the novel two-dimensional layered borophosphate anionic partial structure.

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Article information

DOI: https://doi.org/10.1039/C1CE06233F
Article type: Communication
Submitted: 20 Sep 2011
Accepted: 06 Oct 2011
First published: 19 Oct 2011

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CrystEngComm, 2011,13, 7185-7188

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Ti[BP₂O₇(OH)₃]: The first titanium borophosphate containing novel anionic partial structure

H. Shi, Y. Feng, Q. Huang, D. Qiu, M. Li and K. Liu, CrystEngComm, 2011, 13, 7185 DOI: 10.1039/C1CE06233F

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