Issue 7, 2011
From the journal:

CrystEngComm

Stoichiometry-dominated in situ formation of iodocuprate clusters and dimethyl-2,2′-biimidazoles as building units of coordination architectures†

Ying Cheng,a   Peng Xu,a   You-Bang Dinga  and  Ye-Gao Yin*a  

* Corresponding authors

a Department of Chemistry, Shantou University, Shantou, Guangdong, P. R. China
E-mail: ygyin@stu.edu.cn
Fax: +86-0754-82902767
Tel: +86-0754-82903699

Abstract

Methanothermal reactions of CuI and 2,2′-biimidazole in the molar ratios of 1 : 1 and 3 : 4 gave the luminescent coordination polymers, [Cu8(μ2-I)(μ3-I)6(μ6-I)(1,1′-DMBIM)3]n (1), as a knotted rope, and [Cu4(μ3-I)4(1,3-DMBIM)2]n (2), as a setup of two interpenetrating 66-dia networks (DMBIM = dimethyl-2,2′-biimidazole).

Graphical abstract: Stoichiometry-dominated in situ formation of iodocuprate clusters and dimethyl-2,2′-biimidazoles as building units of coordination architectures

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Article information

DOI
https://doi.org/10.1039/C0CE00938E
Article type
Paper
Submitted
25 Oct 2010
Accepted
11 Jan 2011
First published
23 Feb 2011

CrystEngComm, 2011,13, 2644-2648

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Stoichiometry-dominated in situ formation of iodocuprate clusters and dimethyl-2,2′-biimidazoles as building units of coordination architectures

Y. Cheng, P. Xu, Y. Ding and Y. Yin, CrystEngComm, 2011, 13, 2644 DOI: 10.1039/C0CE00938E

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