Issue 6, 2011
From the journal:

CrystEngComm

Silver-mediated self-assembly of metallosupramolecular networks based on pyrimidine-containing oxacalix[n]aromatics†

Ming-Liang Ma,a   Xiao-Yan Li,a   Xiao-Li Zhao,b   Fang Guo,c   Biao Jiang*c  and  Ke Wen*ac  

* Corresponding authors

a Division of Supramolecular Chemistry and Medicinal Chemistry, Shanghai Key Laboratory of Brain Functional Genomics, Key Laboratory of Brain Functional Genomics, Ministry of Education, East China Normal University, Shanghai, China
E-mail: kwen@brain.ecnu.edu.cn
Fax: +8621-6260-1953
Tel: +8621-6223-7102

b Shanghai Key Laboratory of Green Chemistry and Chemical Processes, and Department of Chemistry, East China Normal University, Shanghai, China

c Center for Nanomedicine, Shanghai Advanced Research Institute, Chinese Academy of Science, Shanghai, China
E-mail: jiangb@sari.ac.cn
Fax: +8621-5080-7562
Tel: +8621- 5080-8085

Abstract

Under self-assembly conditions, the interaction between pyrimidinyl-containing oxacalixaromatics (1 and 2) and silver cation resulted in the formation of two-dimensional coordination networks 3 and 4; single crystal X-ray analysis revealed that complex 3 featured a coordination polymeric structure with ligand 1 arranged in an offset manner along the polymeric chain, while network 4 featured a structure with regular microcyclic channels.

Graphical abstract: Silver-mediated self-assembly of metallosupramolecular networks based on pyrimidine-containing oxacalix[n]aromatics

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Article information

DOI
https://doi.org/10.1039/C0CE00812E
Article type
Communication
Submitted
04 Nov 2010
Accepted
08 Dec 2010
First published
06 Jan 2011

CrystEngComm, 2011,13, 1752-1754

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Silver-mediated self-assembly of metallosupramolecular networks based on pyrimidine-containing oxacalix[n]aromatics

M. Ma, X. Li, X. Zhao, F. Guo, B. Jiang and K. Wen, CrystEngComm, 2011, 13, 1752 DOI: 10.1039/C0CE00812E

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