Issue 9, 2010
From the journal:

CrystEngComm

In situ investigations of the polyoxometalate Trojan Horse compound K7Na[WVI18O56(SO3)2(H2O)2]·20H2O under high temperature and high pressure conditions

Raúl Quesada Cabrera,ab   De-Liang Long,c   Leroy Cronin*c  and  Paul F. McMillan*a  

* Corresponding authors

a Department of Chemistry and Materials Chemistry Centre, Christopher Ingold Laboratories, University College London, London, UK
E-mail: p.f.mcmillan@ucl.ac.uk

b Swiss-Norwegian Beam Lines, ESRF, Boite Postale 220, Grenoble, France

c Department of Chemistry, The University of Glasgow, Glasgow, UK
E-mail: L.Cronin@chem.gla.ac.uk

Abstract

We have used Raman and IR spectroscopy to study the oxidation reaction of sulfite groups in the unique polyoxometalate compound K7Na[WVI18O56(SO3)2(H2O)2]·20H2O with a structure related to the Wells–Dawson type in situ at high temperature and high pressure. The results give new insights into the unusual redox process that occurs in this compound with electrons and O2− ions transferred between the polyoxometalate cluster and SO32−/SO42− groups held within the cage in a process that has been termed the “Trojan Horse” effect.

Graphical abstract: In situ investigations of the polyoxometalate Trojan Horse compound K7Na[WVI18O56(SO3)2(H2O)2]·20H2O under high temperature and high pressure conditions

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Article information

DOI
https://doi.org/10.1039/C003388J
Article type
Paper
Submitted
18 Feb 2010
Accepted
06 May 2010
First published
03 Jun 2010

CrystEngComm, 2010,12, 2568-2572

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In situ investigations of the polyoxometalate Trojan Horse compound K7Na[WVI18O56(SO3)2(H2O)2]·20H2O under high temperature and high pressure conditions

R. Q. Cabrera, D. Long, L. Cronin and P. F. McMillan, CrystEngComm, 2010, 12, 2568 DOI: 10.1039/C003388J

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