Issue 11, 2010
From the journal:

CrystEngComm

Helical channels, low framework density and structure-directing effect: a novel non-centrosymmetric zinc phosphate NIS-4 prepared by ionothermal reaction†

Jing-Dong Feng,ab   Shu-Wei Tang,a   Kui-Zhan Shao,a   Rong-Shun Wang,*a   Chan Yao,a   Hai-Ming Xiea  and  Zhong-Min Su*a  

* Corresponding authors

a Institute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun, P. R. China
E-mail: wangrs@nenu.edu.cn, zmsu@nenu.edu.cn
Fax: (+86) 431-85099511

b Institute of Applied Chemistry, College of Chemistry, Jilin Normal University, Siping, P. R. China

Abstract

A novel non-centrosymmetric zinc phosphate, Zn(HPO4)(H2PO4)·C6H11N2 (denoted NIS-4), was ionothermally synthesized. The framework exhibits fascinating helical channels and remarkably low framework density (FD). Meanwhile, an ionic liquid cation plays a significant structure-directing role during the course of crystallization.

Graphical abstract: Helical channels, low framework density and structure-directing effect: a novel non-centrosymmetric zinc phosphate NIS-4 prepared by ionothermal reaction

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Article information

DOI
https://doi.org/10.1039/C002882G
Article type
Communication
Submitted
10 Feb 2010
Accepted
11 Jun 2010
First published
25 Jun 2010

CrystEngComm, 2010,12, 3448-3451

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Helical channels, low framework density and structure-directing effect: a novel non-centrosymmetric zinc phosphate NIS-4 prepared by ionothermal reaction

J. Feng, S. Tang, K. Shao, R. Wang, C. Yao, H. Xie and Z. Su, CrystEngComm, 2010, 12, 3448 DOI: 10.1039/C002882G

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