Luminescent boracite-like metal–organic frameworks constructed by Cu-centered CuCu4 tetrahedra and CuCu3 triangles with an acentric cubic superlarge cell

Zheng-Ming Hao; Cai-Hong Guo; Hai-Shun Wu; Xian-Ming Zhang

doi:10.1039/B918159H

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Luminescent boracite-like metal–organic frameworks constructed by Cu-centered CuCu₄ tetrahedra and CuCu₃ triangles with an acentric cubic superlarge cell†

Zheng-Ming Hao,^a Cai-Hong Guo,^a Hai-Shun Wu^a and Xian-Ming Zhang*^a

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* Corresponding authors

^a School of Chemistry & Material Science, Shanxi Normal University, Linfen, P. R. China
E-mail: zhangxm@dns.sxnu.edu.cn

Abstract

Solvothermal treatment of copper halides and 3-amino-5-mercapto-1,2,4-triazole (H₂amtz) produced three isostructural complexes [Cu₃₁X₄(H_1.55amtz)₂₄](SO₄)₈·xDMF [X = Cl, Br and I, x ∼ 32], which show 3-D networks with bor topology constructed by Cu-centered CuCu₄ tetrahedra and CuCu₃ triangles with an acentric cubic superlarge cell.

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Article information

DOI: https://doi.org/10.1039/B918159H
Article type: Communication
Submitted: 02 Sep 2009
Accepted: 16 Sep 2009
First published: 25 Sep 2009

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CrystEngComm, 2010,12, 55-58

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Luminescent boracite-like metal–organic frameworks constructed by Cu-centered CuCu₄ tetrahedra and CuCu₃ triangles with an acentric cubic superlarge cell

Z. Hao, C. Guo, H. Wu and X. Zhang, CrystEngComm, 2010, 12, 55 DOI: 10.1039/B918159H

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