Issue 10, 2009
From the journal:

CrystEngComm

Magnetization-induced second harmonic generation in a three-dimensional manganese octacyanoniobate-based pyroelectric ferrimagnet

Yoshihide Tsunobuchi,a   Wataru Kosaka,a   Tomohiro Nuidaa  and  Shin-ichi Ohkoshi*a  

* Corresponding authors

a Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, Japan
E-mail: ohkoshi@chem.s.u-tokyo.ac.jp

Abstract

The magnetization-induced second harmonic generation (MSHG) is observed using a three-dimensional MnII–NbIV pyroelectric ferrimagnet, [{MnII(H2O)2}{MnII(pyrazine)(H2O)2}{NbIV(CN)8}]·4H2O, in which electric polarization is along the b-axis and the magnetic easy axis is along the a-axis. The SH intensity gradually increases due to superparamagnetism below 90 K, and then rapidly increases near the Curie temperature (TC = 48 K) due to spontaneous magnetization.

Graphical abstract: Magnetization-induced second harmonic generation in a three-dimensional manganese octacyanoniobate-based pyroelectric ferrimagnet

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Article information

DOI
https://doi.org/10.1039/B906778G
Article type
Communication
Submitted
03 Apr 2009
Accepted
16 Jun 2009
First published
01 Jul 2009

CrystEngComm, 2009,11, 2051-2053

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Magnetization-induced second harmonic generation in a three-dimensional manganese octacyanoniobate-based pyroelectric ferrimagnet

Y. Tsunobuchi, W. Kosaka, T. Nuida and S. Ohkoshi, CrystEngComm, 2009, 11, 2051 DOI: 10.1039/B906778G

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