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Issue 8, 2009
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Unusual anion effect on the direction of three-dimensional (3-D) channel-like silver(I) coordination frameworks with isonicotinic acid N-oxide

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Abstract

Reaction of isonicotinic acid N-oxide (HINO) with AgClO4 or AgBF4 under similar conditions unexpectedly generates two distinct crystalline products {[Ag3(INO)2(HINO)2]·(ClO4)}n (1) and {[Ag(INO)]·(H2O)}n (2). Complex 1 consists of a 3-D cationic net with mixed-connected topology and the included perchlorate counterions, whereas 2 has a 3-D neutral open framework (4-connected crb topology) with the accommodation of lattice water. The anion exchange/competition and guest desorption/adsorption behavior have also been thoroughly explored.

Graphical abstract: Unusual anion effect on the direction of three-dimensional (3-D) channel-like silver(I) coordination frameworks with isonicotinic acid N-oxide

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Publication details

The article was received on 16 Feb 2009, accepted on 24 Apr 2009 and first published on 26 May 2009


Article type: Communication
DOI: 10.1039/B903074C
Citation: CrystEngComm, 2009,11, 1536-1540
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    Unusual anion effect on the direction of three-dimensional (3-D) channel-like silver(I) coordination frameworks with isonicotinic acid N-oxide

    M. Du, C. Li and J. Guo, CrystEngComm, 2009, 11, 1536
    DOI: 10.1039/B903074C

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