Issue 6, 2009

Silver⋯X–aryl (X = I and Br) interaction in a network assembly with a flexible polynuclear silver–ethynide supramolecular synthon

Abstract

In a series of five new silver(I) ethynide complexes, the invariable appearance of the μ4 and μ5 ligation modes of the ethynide moiety affirms the general utility of the supramolecular synthon p-X–C6H5OCH2C≡C⊃Agn (X = I, Br; n = 4, 5) in the assembly of coordination networks, in which the silver⋯halogen–aryl interaction plays an important role.

Graphical abstract: Silver⋯X–aryl (X = I and Br) interaction in a network assembly with a flexible polynuclear silver–ethynide supramolecular synthon

Supplementary files

Article information

Article type
Paper
Submitted
07 Jan 2009
Accepted
13 Jan 2009
First published
10 Feb 2009

CrystEngComm, 2009,11, 1061-1067

Silver⋯X–aryl (X = I and Br) interaction in a network assembly with a flexible polynuclear silver–ethynide supramolecular synthon

S. Zang, P. Cheng and T. C. W. Mak, CrystEngComm, 2009, 11, 1061 DOI: 10.1039/B900308H

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