An unprecedented bridging [Ag2(NO3)6]4− anion as a component of an infinite silver(I) molecular ladder incorporating a dinuclear cationic silver complex of a bis-dipyridylamine ligand

Bianca Antonioli; Jack K. Clegg; David J. Bray; Kerstin Gloe; Karsten Gloe; Holger Heßke; Leonard F. Lindoy

doi:10.1039/B611270F

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An unprecedented bridging [Ag₂(NO₃)₆]⁴⁻ anion as a component of an infinite silver(i) molecular ladder incorporating a dinuclear cationic silver complex of a bis-dipyridylamine ligand†

Bianca Antonioli,^a Jack K. Clegg,^b David J. Bray,^b Kerstin Gloe,^a Karsten Gloe,*^a Holger Heßke^a and Leonard F. Lindoy*^b

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* Corresponding authors

^a Department of Chemistry, TU Dresden, Dresden, Germany
E-mail: karsten.gloe@chemie.tu-dresden.de

^b Centre for Heavy Metals Research, School of Chemistry, University of Sydney, NSW, Australia
E-mail: lindoy@chem.usyd.edu.au

Abstract

The interaction of silver(I) nitrate with the polypyridyl ligand (L) formed from two dipyridylamine units joined at their secondary amines by a 2,6-lutidinyl bridge results in a molecular ladder motif that consists of pairs of cationic [Ag₂(L)MeCN]²⁺ units bridged by an unprecedented [Ag₂(NO₃)₆]⁴⁻ anion.

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Article information

DOI: https://doi.org/10.1039/B611270F
Article type: Communication
Submitted: 24 May 2006
Accepted: 08 Aug 2006
First published: 29 Aug 2006

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CrystEngComm, 2006,8, 748-750

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An unprecedented bridging [Ag₂(NO₃)₆]⁴⁻ anion as a component of an infinite silver(I) molecular ladder incorporating a dinuclear cationic silver complex of a bis-dipyridylamine ligand

B. Antonioli, J. K. Clegg, D. J. Bray, K. Gloe, K. Gloe, H. Heßke and L. F. Lindoy, CrystEngComm, 2006, 8, 748 DOI: 10.1039/B611270F

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