Issue 9, 2006
From the journal:

CrystEngComm

[Fe(qdt)2]− salts; an undimerised FeIII bisdithiolene complex stabilised by cation interactions

D. Simão,a   J. A. Ayllón,†b   S. Rabaça,b   M. J. Figueira,b   I. C. Santos,b   R. T. Henriquesbc  and  M. Almeida*b  

* Corresponding authors

a Departamento de Engenharia Química, Instituto Superior Técnico, Lisboa, Portugal

b Dept. Química, Instituto Tecnológico e Nuclear/CFMCUL, Sacavém, Portugal
E-mail: malmeida@itn.pt
Fax: +351 219941455
Tel: +351 219941455

c Instituto de Telecomunicações, Pólo de Lisboa, Lisboa, Portugal

Abstract

(n-Bu)4N[Fe(qdt)2] provides the first example of an undimerised FeIII bisdithiolene complex with well isolated square planar coordinated [Fe(qdt)2]− units, due to short apical Fe⋯H, Fe⋯C and S⋯H contacts with the cations, while the tetraphenylarsonium salt of this complex presents the usual dimerisation as [Fe(qdt)2]22−, with square-based pyramidal coordination of Fe.

Graphical abstract: [Fe(qdt)2]− salts; an undimerised FeIII bisdithiolene complex stabilised by cation interactions

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Article information

DOI
https://doi.org/10.1039/B602268E
Article type
Communication
Submitted
15 Feb 2006
Accepted
24 Jul 2006
First published
31 Jul 2006

CrystEngComm, 2006,8, 658-661

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[Fe(qdt)2]− salts; an undimerised FeIII bisdithiolene complex stabilised by cation interactions

D. Simão, J. A. Ayllón, S. Rabaça, M. J. Figueira, I. C. Santos, R. T. Henriques and M. Almeida, CrystEngComm, 2006, 8, 658 DOI: 10.1039/B602268E

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