Issue 59, 2018

Remarkable multimember-ring configurations in a new family of Na7MIISb5S12 (MII = Zn, Cd, Hg) exhibiting various three-dimensional tunnel structures

Abstract

A new family of Na7MIISb5S12 (MII = Zn, Cd and Hg) are the first examples exhibiting the unusual 12 + 12 multimember-ring (MR) configuration and an interesting (MII/Sb)3S9 trimer. Moreover, ELF and EDD calculations also reveal that the tetrahedral configurations for the MII/Sb atoms are reasonable and their large birefringences originate from the stereochemically active lone pair effect of the Sb atoms.

Graphical abstract: Remarkable multimember-ring configurations in a new family of Na7MIISb5S12 (MII = Zn, Cd, Hg) exhibiting various three-dimensional tunnel structures

Supplementary files

Article information

Article type
Communication
Submitted
11 Jun 2018
Accepted
03 Jul 2018
First published
03 Jul 2018

Chem. Commun., 2018,54, 8269-8272

Remarkable multimember-ring configurations in a new family of Na7MIISb5S12 (MII = Zn, Cd, Hg) exhibiting various three-dimensional tunnel structures

K. Wu, B. Zhang, Z. Yang and S. Pan, Chem. Commun., 2018, 54, 8269 DOI: 10.1039/C8CC04639E

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