Photocatalytic chemoselective cleavage of C–O bonds under hydrogen gas- and acid-free conditions

Kazuya Imamura; Hiroko Kato; Yuichiro Wada; Kazuhiro Makabe; Ayumu Onda; Atsuhiro Tanaka; Hiroshi Kominami; Katsutoshi Sato; Katsutoshi Nagaoka

doi:10.1039/C8CC03362E

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Photocatalytic chemoselective cleavage of C–O bonds under hydrogen gas- and acid-free conditions†

Kazuya Imamura,

*^a Hiroko Kato,^b Yuichiro Wada,^b Kazuhiro Makabe,^a Ayumu Onda,

^a Atsuhiro Tanaka,

^c Hiroshi Kominami,

^c Katsutoshi Sato

^bd and Katsutoshi Nagaoka

*^b

Author affiliations

* Corresponding authors

^a Research Laboratory of Hydrothermal Chemistry, Department of Chemistry and Biotechnology, Faculty of Science and Technology, Kochi University, 2-5-1 Akebono-cho, Kochi, Japan
E-mail: imamura-kazuya@kochi-u.ac.jp

^b Department of Integrated Science and Technology, Faculty of Science and Technology, Oita University, 700 Dannoharu, Oita 870-1154, Japan
E-mail: nagaoka@oita-u.ac.jp

^c Department of Applied Chemistry, Faculty of Science and Engineering, Kindai University, 3-4-1 Kowakae, Higashiosaka, Osaka 577-8502, Japan

^d Elements Strategy Initiative for Catalysts and Batteries, Kyoto University, 1-30 Goryo-Ohara, Nishikyo-ku, Kyoto 615-8245, Japan

Abstract

In the presence of a palladium-loaded TiO₂ photocatalyst, the cleavage of benzyl phenyl ether in low-molecular-weight alcohol solvents under de-aerated conditions afforded toluene and phenol simultaneously in a 1 : 1 molar ratio.

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Article information

DOI: https://doi.org/10.1039/C8CC03362E
Article type: Communication
Submitted: 25 Apr 2018
Accepted: 15 May 2018
First published: 17 May 2018

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Chem. Commun., 2018,54, 7298-7301

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Photocatalytic chemoselective cleavage of C–O bonds under hydrogen gas- and acid-free conditions

K. Imamura, H. Kato, Y. Wada, K. Makabe, A. Onda, A. Tanaka, H. Kominami, K. Sato and K. Nagaoka, Chem. Commun., 2018, 54, 7298 DOI: 10.1039/C8CC03362E

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Chemical Communications

Photocatalytic chemoselective cleavage of C–O bonds under hydrogen gas- and acid-free conditions†

Abstract

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Photocatalytic chemoselective cleavage of C–O bonds under hydrogen gas- and acid-free conditions

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