Perfect balance harmony in Ba2NO3(OH)3: a beryllium-free nitrate as a UV nonlinear optical material

Xuehua Dong; Ling Huang; Qingyu Liu; Hongmei Zeng; Zhien Lin; Dingguo Xu; Guohong Zou

doi:10.1039/C8CC03007C

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Perfect balance harmony in Ba₂NO₃(OH)₃: a beryllium-free nitrate as a UV nonlinear optical material†

Xuehua Dong,^a Ling Huang,^b Qingyu Liu,^a Hongmei Zeng,^a Zhien Lin,

^a Dingguo Xu

^a and Guohong Zou

*^a

Author affiliations

* Corresponding authors

^a College of Chemistry, Sichuan University, Chengdu, P. R. China
E-mail: zough@scu.edu.cn

^b College of Chemistry and Materials Science, Sichuan Normal University, Chengdu, P. R. China

Abstract

A promising UV nonlinear optical material, beryllium-free nitrate Ba₂NO₃(OH)₃, has been synthesized via modified high-temperature solid state reactions in a self-made high-pressure apparatus which exhibits a perfect balance of a large second harmonic generation coefficient, an appropriate birefringence for phase matching, a short UV absorption cutoff edge and physicochemical stabilities.

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Article information

DOI: https://doi.org/10.1039/C8CC03007C
Article type: Communication
Submitted: 15 Apr 2018
Accepted: 11 May 2018
First published: 11 May 2018

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Chem. Commun., 2018,54, 5792-5795

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Perfect balance harmony in Ba₂NO₃(OH)₃: a beryllium-free nitrate as a UV nonlinear optical material

X. Dong, L. Huang, Q. Liu, H. Zeng, Z. Lin, D. Xu and G. Zou, Chem. Commun., 2018, 54, 5792 DOI: 10.1039/C8CC03007C

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Chemical Communications