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Issue 50, 2018
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Proton and ammonia intercalation into layered iron chalcogenides

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Abstract

Structurally related to the iron-based superconductors, two new intercalated iron chalcogenides (H0.5NH3)Fe2Ch2 where Ch = S, Se have been prepared. By topochemical conversion, the protons were exchanged by lithium to form (Li0.5NH3)Fe2Ch2. Hydrogen bonding plays a significant role in the guest–host interactions of these intercalated phases.

Graphical abstract: Proton and ammonia intercalation into layered iron chalcogenides

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Publication details

The article was received on 27 Mar 2018, accepted on 30 Apr 2018 and first published on 02 May 2018


Article type: Communication
DOI: 10.1039/C8CC02436G
Citation: Chem. Commun., 2018,54, 6895-6898
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    Proton and ammonia intercalation into layered iron chalcogenides

    X. Zhou, B. Wilfong, S. Liou, H. Hodovanets, C. M. Brown and E. E. Rodriguez, Chem. Commun., 2018, 54, 6895
    DOI: 10.1039/C8CC02436G

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