Issue 47, 2018

A luminescent [Pd4Ru8]24+ supramolecular cage

Abstract

A phosphorescent cage of the form [Pd4Ru8]24+ is reported. The cage was formed using the metalloligand [Ru(dtbubpy)2(qpy)]2+, where qpy = 4,4′:2′,2′′:4′′,4′′′-quaterpyridine and dtbubpy = 4,4′-di-tert-butyl-2,2′-bipyridine. The cage has been characterised by NMR, ESI-MS, TEM and X-ray diffraction analyses and its emission properties elucidated by steady-state and time-resolved emission spectroscopy.

Graphical abstract: A luminescent [Pd4Ru8]24+ supramolecular cage

Supplementary files

Article information

Article type
Communication
Submitted
15 Mar 2018
Accepted
14 May 2018
First published
14 May 2018

Chem. Commun., 2018,54, 6016-6019

A luminescent [Pd4Ru8]24+ supramolecular cage

D. Rota Martir, D. B. Cordes, A. M. Z. Slawin, D. Escudero, D. Jacquemin, S. L. Warriner and E. Zysman-Colman, Chem. Commun., 2018, 54, 6016 DOI: 10.1039/C8CC02104J

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