Issue 34, 2018

Relevance of ion clusters for Li transport at elevated salt concentrations in [Pyr12O1][FTFSI] ionic liquid-based electrolytes

Abstract

In binary ionic liquid/Li salt mixtures with the novel asymmetric anion FTFSI, electrophoretic mobility μi values of all ion species were determined using electrophoretic NMR. Li was determined to migrate in negatively charged Li-anion clusters towards the anode. This vehicular transport mechanism was shown to have decreasing relevance at elevated salt concentrations.

Graphical abstract: Relevance of ion clusters for Li transport at elevated salt concentrations in [Pyr12O1][FTFSI] ionic liquid-based electrolytes

Supplementary files

Article information

Article type
Communication
Submitted
19 Feb 2018
Accepted
27 Mar 2018
First published
28 Mar 2018

Chem. Commun., 2018,54, 4278-4281

Relevance of ion clusters for Li transport at elevated salt concentrations in [Pyr12O1][FTFSI] ionic liquid-based electrolytes

M. Brinkkötter, G. A. Giffin, A. Moretti, S. Jeong, S. Passerini and M. Schönhoff, Chem. Commun., 2018, 54, 4278 DOI: 10.1039/C8CC01416G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements