Issue 23, 2018

Synthesis, crystal structure and reactivity of η2-thiophyne Ni complexes

Abstract

The first synthesis and crystal structures of five-membered ring aryne complexes, Ni(dcpe)(η2-thiophyne) and Ni(dcpe)(η2-benzo[b]thiophyne), are described. The aryne fragments retain considerable aromatic character and the two coordinated carbon atoms exhibit distinct reactivity due to their asymmetric nature.

Graphical abstract: Synthesis, crystal structure and reactivity of η2-thiophyne Ni complexes

Supplementary files

Article information

Article type
Communication
Submitted
27 Jan 2018
Accepted
20 Feb 2018
First published
23 Feb 2018

Chem. Commun., 2018,54, 2918-2921

Synthesis, crystal structure and reactivity of η2-thiophyne Ni complexes

M. Terada, Y. Nishii and M. Miura, Chem. Commun., 2018, 54, 2918 DOI: 10.1039/C8CC00705E

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