Issue 22, 2018

Incorporation of an intact dimeric Zr12 oxo cluster from a molecular precursor in a new zirconium metal–organic framework

Abstract

Two zirconium–organic frameworks were synthesized by exchanging the acetate ligands in [Zr12O8(OH)8(CH3COO)24] with polydentate linkers. Partial substitution of acetate groups by a phosphine based linker yielded a new porous framework with this unique dimeric Zr12 cluster unit as molecular building block. More exhaustive substitution of acetate resulted in cleavage of the Zr12 unit and formation of UiO-67.

Graphical abstract: Incorporation of an intact dimeric Zr12 oxo cluster from a molecular precursor in a new zirconium metal–organic framework

Supplementary files

Article information

Article type
Communication
Submitted
22 Jan 2018
Accepted
18 Feb 2018
First published
19 Feb 2018

Chem. Commun., 2018,54, 2735-2738

Incorporation of an intact dimeric Zr12 oxo cluster from a molecular precursor in a new zirconium metal–organic framework

A. A. Bezrukov, K. W. Törnroos, E. Le Roux and P. D. C. Dietzel, Chem. Commun., 2018, 54, 2735 DOI: 10.1039/C8CC00507A

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