Issue 18, 2018

The homometallic polyoxotungstate archetype {P4W24}

Abstract

Functionalization with terminal organophosphonate and -arsonate groups allows for crystallization and structural characterization of elusive homometallic phosphotungstates of the {PV4WVI24} archetype. 31P NMR measurements reveal moderate stability in aqueous solution for the [(PhPO)2P4W24O92]16− derivative, enabling consecutive reactions as exemplified by the formation of a CoII-{P4W24}-based coordination polymer.

Graphical abstract: The homometallic polyoxotungstate archetype {P4W24}

Supplementary files

Article information

Article type
Communication
Submitted
29 Nov 2017
Accepted
26 Dec 2017
First published
02 Jan 2018

Chem. Commun., 2018,54, 2216-2219

The homometallic polyoxotungstate archetype {P4W24}

X. Yi, N. V. Izarova and P. Kögerler, Chem. Commun., 2018, 54, 2216 DOI: 10.1039/C7CC09175C

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