A strategy for generating aryl radicals from arylborates through organic photoredox catalysis: photo-Meerwein type arylation of electron-deficient alkenes

Y. Iwata; Y. Tanaka; S. Kubosaki; T. Morita; Y. Yoshimi

doi:10.1039/C7CC09140K

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A strategy for generating aryl radicals from arylborates through organic photoredox catalysis: photo-Meerwein type arylation of electron-deficient alkenes†

Y. Iwata,^a Y. Tanaka,^a S. Kubosaki,^a T. Morita^a and Y. Yoshimi

*^a

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* Corresponding authors

^a Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, University of Fukui, 3-9-1 Bunkyo, Fukui 910-8507, Japan
E-mail: yyoshimi@u-fukui.ac.jp

Abstract

Photoinduced reactions of arylboronic acids with electron deficient alkenes under mild organic photoredox catalysis conditions lead to the formation of Meerwein arylation type adducts via the generation of aryl radicals.

This article is part of the themed collection: Editor’s Choice: Main group reagents and catalysts in organic reactions

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Article information

DOI: https://doi.org/10.1039/C7CC09140K
Article type: Communication
Submitted: 28 Nov 2017
Accepted: 10 Jan 2018
First published: 10 Jan 2018

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Chem. Commun., 2018,54, 1257-1260

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A strategy for generating aryl radicals from arylborates through organic photoredox catalysis: photo-Meerwein type arylation of electron-deficient alkenes

Y. Iwata, Y. Tanaka, S. Kubosaki, T. Morita and Y. Yoshimi, Chem. Commun., 2018, 54, 1257 DOI: 10.1039/C7CC09140K

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Chemical Communications

A strategy for generating aryl radicals from arylborates through organic photoredox catalysis: photo-Meerwein type arylation of electron-deficient alkenes†

Abstract

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A strategy for generating aryl radicals from arylborates through organic photoredox catalysis: photo-Meerwein type arylation of electron-deficient alkenes

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