Issue 6, 2018

Thermally activated delayed fluorescence of a Zr-based metal–organic framework

Abstract

The first metal–organic framework exhibiting thermally activated delayed fluorescence (TADF) was developed. The zirconium-based framework (UiO-68-dpa) uses a newly designed linker composed of a terphenyl backbone, an electron-accepting carboxyl group, and an electron-donating diphenylamine and exhibits green TADF emission with a photoluminescence quantum yield of 30% and high thermal stability.

Graphical abstract: Thermally activated delayed fluorescence of a Zr-based metal–organic framework

Supplementary files

Article information

Article type
Communication
Submitted
08 Nov 2017
Accepted
22 Dec 2017
First published
22 Dec 2017

Chem. Commun., 2018,54, 631-634

Thermally activated delayed fluorescence of a Zr-based metal–organic framework

H. Mieno, R. Kabe, M. D. Allendorf and C. Adachi, Chem. Commun., 2018, 54, 631 DOI: 10.1039/C7CC08595H

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