Issue 99, 2017

A meta-selective-C–H alkenylation of phenol-derivatives employing a traceless organosilicon template

Abstract

A traceless organosilicon template-directed meta-selective-C–H alkenylation of phenols was realized with good yields and high selectivities. The template was readily removable through F-promoted O–Si cleavage under extremely mild conditions or recyclable through a p-TSA catalyzed process. The product was successfully applied in the preparation of a series of meta-alkenylated aromatic compounds.

Graphical abstract: A meta-selective-C–H alkenylation of phenol-derivatives employing a traceless organosilicon template

Supplementary files

Article information

Article type
Communication
Submitted
11 Sep 2017
Accepted
09 Nov 2017
First published
17 Nov 2017

Chem. Commun., 2017,53, 13209-13212

A meta-selective-C–H alkenylation of phenol-derivatives employing a traceless organosilicon template

R. Mi, J. Sun, F. E. Kühn, M. Zhou and Z. Xu, Chem. Commun., 2017, 53, 13209 DOI: 10.1039/C7CC07093D

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