[Hyp-Au-Sn9(Hyp)3-Au-Sn9(Hyp)3-Au-Hyp]−: the longest intermetalloid chain compound of tin

Mareike Binder; Claudio Schrenk; Theresa Block; Rainer Pöttgen; Andreas Schnepf

doi:10.1039/C7CC07029B

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[Hyp-Au-Sn₉(Hyp)₃-Au-Sn₉(Hyp)₃-Au-Hyp]⁻: the longest intermetalloid chain compound of tin†

Mareike Binder,^a Claudio Schrenk,

^a Theresa Block,^b Rainer Pöttgen^b and Andreas Schnepf

*^a

Author affiliations

* Corresponding authors

^a Institut für Anorganische Chemie, Universität Tübingen, Auf der Morgenstelle 18, D-72076 Tübingen, Germany
E-mail: andreas.schnepf@uni-tuebingen.de
Fax: +49 (7071) 28-2436
Tel: +49 (7071) 29-76635

^b Institut für Anorganische und Analytische Chemie, Universität Münster, Corrensstrasse 30, D-48149 Münster, Germany

Abstract

The reaction of the metalloid tin cluster [Sn₁₀(Hyp)₄]²⁻ with (Ph₃P)Au-SHyp (Hyp = Si(SiMe₃)₃) gave an intermetalloid cluster [Au₃Sn₁₈(Hyp)₈]⁻1, which is the longest intermetalloid chain compound of tin to date. 1 shows a structural resemblance to binary AuSn phases, which is expected for intermetalloid clusters.

This article is part of the themed collection: Philip Power at 65: an icon of organometallic chemistry

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Article information

DOI: https://doi.org/10.1039/C7CC07029B
Article type: Communication
Submitted: 07 Sep 2017
Accepted: 23 Sep 2017
First published: 25 Sep 2017

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Chem. Commun., 2017,53, 11314-11317

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[Hyp-Au-Sn₉(Hyp)₃-Au-Sn₉(Hyp)₃-Au-Hyp]⁻: the longest intermetalloid chain compound of tin

M. Binder, C. Schrenk, T. Block, R. Pöttgen and A. Schnepf, Chem. Commun., 2017, 53, 11314 DOI: 10.1039/C7CC07029B

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