Issue 88, 2017
From the journal:

Chemical Communications

Th(iv) and Ce(iv) napthylsalophen sandwich complexes: characterization of unusual thorium fluorescence in solution and solid-state†

E. E. Hardy,a   K. M. Wyss,a   J. D. Gorden,a   I. R. Ariyarathna,a   E. Miliordosa  and  A. E. V. Gorden ORCID logo *a  

* Corresponding authors

a Department of Chemistry and Biochemistry, Auburn University, 179 Chemistry Building, Auburn, AL, USA
E-mail: anne.gorden@auburn.edu

Abstract

The synthesis, characterization, and electronic spectroscopy of two ML2 sandwich complexes, where M = Ce(IV) or Th(IV) and L = napthylsalophen2− are described. The ThL2 complex, unlike the isovalent CeL2, complex possesses unusual fluorescence properties in both solution and solid-state. These observations are explained with TD-DFT.

Graphical abstract: Th(iv) and Ce(iv) napthylsalophen sandwich complexes: characterization of unusual thorium fluorescence in solution and solid-state

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Article information

DOI
https://doi.org/10.1039/C7CC06868A
Article type
Communication
Submitted
02 Sep 2017
Accepted
11 Oct 2017
First published
11 Oct 2017

Chem. Commun., 2017,53, 11984-11987

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Th(IV) and Ce(IV) napthylsalophen sandwich complexes: characterization of unusual thorium fluorescence in solution and solid-state

E. E. Hardy, K. M. Wyss, J. D. Gorden, I. R. Ariyarathna, E. Miliordos and A. E. V. Gorden, Chem. Commun., 2017, 53, 11984 DOI: 10.1039/C7CC06868A

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