Issue 96, 2017
From the journal:

Chemical Communications

Direct alkylheteroarylation of alkenes via photoredox mediated C–H functionalization†

Lijun Gu, ORCID logo *a   Ying Gao,b   Xianhong Ai,a   Cheng Jin, ORCID logo c   Yonghui He,a   Ganpeng Lia  and  Minglong Yuand  

* Corresponding authors

a Key Laboratory of Chemistry in Ethnic Medicinal Resources, State Ethnic Affairs Commission & Ministry of Education, Yunnan Minzu University, Kunming, Yunnan, China
E-mail: gulijun2005@126.com

b Merck Sharp & Dohme R & D (China) Company Limited, Beijing 100012, China

c New United Group Company Limited, Changzhou, Jiangsu 213166, China

d Engineering Research Center of Biopolymer Functional Materials of Yunnan, Yunnan Minzu University, Kunming, Yunnan, China

Abstract

The direct alkylheteroarylation of alkenes with cyclic and acyclic ethers via distal heteroaryl ipso-migration has been accomplished through the design of a photoredox-mediated C–H functionalization pathway. The use of inexpensive ethers as radical precursors combined with a straightforward method makes this a practical approach.

Graphical abstract: Direct alkylheteroarylation of alkenes via photoredox mediated C–H functionalization

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Article information

DOI
https://doi.org/10.1039/C7CC06484E
Article type
Communication
Submitted
18 Aug 2017
Accepted
10 Nov 2017
First published
20 Nov 2017

Chem. Commun., 2017,53, 12946-12949

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Direct alkylheteroarylation of alkenes via photoredox mediated C–H functionalization

L. Gu, Y. Gao, X. Ai, C. Jin, Y. He, G. Li and M. Yuan, Chem. Commun., 2017, 53, 12946 DOI: 10.1039/C7CC06484E

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