Issue 94, 2017
From the journal:

Chemical Communications

Reversible regulating of crystal structures based on isomerization of phenylhydrazones†

Lulu Ma, ORCID logo *a   Zexing Yuan,a   Zhenguo Huang,a   Jingyi Jin,a   Duxia Cao, ORCID logo a   Ruifang Guan, ORCID logo a   Qifeng Chen ORCID logo *a  and  Xuan Sun ORCID logo b  

* Corresponding authors

a School of Material Science and Engineering, University of Jinan, No. 336, West Road of Nan Xinzhuang, Jinan, Shandong, P. R. China
E-mail: mse_mall@ujn.edu.cn, qfchen@126.com

b Key Laboratory of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, 27 Shanda Nanlu, Jinan, Shandong, P. R. China

Abstract

Reversible crystal transformation for phenylhydrazones 1 between the orthorhombic microporous 1-E crystal and monoclinic herringbone 1-Z crystal induced by light and heating has been demonstrated. Other than the inherent single-molecular photoreactivity, the weak intermolecular interactions and loose stacking of porous 1-E crystal favor the efficient solid-state photoisomerization.

Graphical abstract: Reversible regulating of crystal structures based on isomerization of phenylhydrazones

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Article information

DOI
https://doi.org/10.1039/C7CC06374A
Article type
Communication
Submitted
15 Aug 2017
Accepted
23 Oct 2017
First published
23 Oct 2017

Chem. Commun., 2017,53, 12630-12633

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Reversible regulating of crystal structures based on isomerization of phenylhydrazones

L. Ma, Z. Yuan, Z. Huang, J. Jin, D. Cao, R. Guan, Q. Chen and X. Sun, Chem. Commun., 2017, 53, 12630 DOI: 10.1039/C7CC06374A

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