Rapid and ordered carbonylation and oxygenation of a cobalt(II) methyl

Regina R. Reinig; Ellie L. Fought; Arkady Ellern; Theresa L. Windus; Aaron D. Sadow

doi:10.1039/C7CC06339C

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Rapid and ordered carbonylation and oxygenation of a cobalt(ii) methyl†

Regina R. Reinig,^ab Ellie L. Fought,^ab Arkady Ellern,^a Theresa L. Windus^ab and Aaron D. Sadow

*^ab

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* Corresponding authors

^a Department of Chemistry, 1605 Gilman Hall, Iowa State University, Ames, IA 50011, USA
E-mail: sadow@iastate.edu

^b US DOE Ames Laboratory, Iowa State University, Ames, IA 50011, USA

Abstract

The oxidative carbonylation of To^MCoMe (1; To^M = tris(4,4-dimethyl-2-oxazolinyl)phenylborate) involves its rapid, reversible reaction with CO to form To^MCo{C(O)Me}CO (2) followed by rapid reaction with O₂ yielding To^MCoOAc (3), in contrast to the slow direct carboxylation of To^MCoMe by CO₂.

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DOI: https://doi.org/10.1039/C7CC06339C
Article type: Communication
Submitted: 13 Aug 2017
Accepted: 15 Sep 2017
First published: 15 Sep 2017

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Chem. Commun., 2017,53, 11020-11023

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Rapid and ordered carbonylation and oxygenation of a cobalt(II) methyl

R. R. Reinig, E. L. Fought, A. Ellern, T. L. Windus and A. D. Sadow, Chem. Commun., 2017, 53, 11020 DOI: 10.1039/C7CC06339C

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Chemical Communications

Rapid and ordered carbonylation and oxygenation of a cobalt(ii) methyl†

Abstract

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Rapid and ordered carbonylation and oxygenation of a cobalt(II) methyl

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