Issue 92, 2017
From the journal:

Chemical Communications

The active site for the water oxidising anodic iridium oxide probed through in situ Raman spectroscopy†

Zoran Pavlovic, ORCID logo a   Chinmoy Ranjan, ORCID logo *a   Maurice van Gastel ORCID logo a  and  Robert Schlögla  

* Corresponding authors

a Department of Heterogeneous Catalysis, Max Planck Institute for Chemical Energy Conversion, Stiftstrasse 34-36, Muelheim and Ruhr, Germany
E-mail: chinmoy.ranjan@cec.mpg.de

Abstract

The structure of anodic iridium oxide (IrOx) under water oxidation was explored using in situ Raman spectroscopy and theoretical calculations. Isotopic substitution experiments and theoretical calculations confirmed formation of an Ir[double bond, length as m-dash]O species during oxygen evolution reaction.

Graphical abstract: The active site for the water oxidising anodic iridium oxide probed through in situ Raman spectroscopy

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Article information

DOI
https://doi.org/10.1039/C7CC05669A
Article type
Communication
Submitted
25 Aug 2017
Accepted
09 Oct 2017
First published
09 Oct 2017
This article is Open Access
Creative Commons BY license

Chem. Commun., 2017,53, 12414-12417

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The active site for the water oxidising anodic iridium oxide probed through in situ Raman spectroscopy

Z. Pavlovic, C. Ranjan, M. van Gastel and R. Schlögl, Chem. Commun., 2017, 53, 12414 DOI: 10.1039/C7CC05669A

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