Issue 77, 2017

Hetero-metallic, functionalizable polyoxomolybdate clusters via a “top-down” synthetic method

Abstract

Two bi-metallic, organophosphonate-stabilised sandwich-type polyoxomolybdate clusters, [Mo6Cu4O16(OH)2(C4H9PO3)4(C5H5N)2 (CH3O)4(H2O)]2− and [Mo7Cu7O19(OH)(CH3O)7(C4H9PO3)6(C5H5N)2]2−, are reported. These compounds are accessed via the “top-down” in situ disassembly of the [Mo6O19]2− Lindqvist species into reactive oligomers, followed by subsequent reassembly with polynuclear CuII assemblies to form the reported compounds.

Graphical abstract: Hetero-metallic, functionalizable polyoxomolybdate clusters via a “top-down” synthetic method

Supplementary files

Article information

Article type
Communication
Submitted
15 Jul 2017
Accepted
01 Sep 2017
First published
01 Sep 2017

Chem. Commun., 2017,53, 10660-10663

Hetero-metallic, functionalizable polyoxomolybdate clusters via a “top-down” synthetic method

C. Healy, B. Twamley, M. Venkatesan, S. Schmidt, T. Gunnlaugsson and W. Schmitt, Chem. Commun., 2017, 53, 10660 DOI: 10.1039/C7CC05498J

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