Nonhelical heterometallic [Mo2M(npo)4(NCS)2] string complexes (M = Fe, Co, Ni) with high single-molecule conductance

Wei-Cheng Chang; Che-Wei Chang; Marc Sigrist; Shao-An Hua; Tsai-Jung Liu; Gene-Hsiang Lee; Bih-Yaw Jin; Chun-hsien Chen; Shie-Ming Peng

doi:10.1039/C7CC05449A

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Nonhelical heterometallic [Mo₂M(npo)₄(NCS)₂] string complexes (M = Fe, Co, Ni) with high single-molecule conductance†

Wei-Cheng Chang,

^a Che-Wei Chang,^a Marc Sigrist,^b Shao-An Hua,^a Tsai-Jung Liu,^a Gene-Hsiang Lee,^a Bih-Yaw Jin,*^a Chun-hsien Chen

*^a and Shie-Ming Peng*^ab

Author affiliations

* Corresponding authors

^a Department of Chemistry and Center for Emerging Material and Advanced Devices, National Taiwan University, Taipei, Taiwan
E-mail: smpeng@ntu.edu.tw, chhchen@ntu.edu.tw, byjin@ntu.edu.tw
Fax: +886-2-83693765

^b Institute of Chemistry, Academia Sinica, Taipei, Taiwan

Abstract

Using the planar 1,8-naphthyridin-2(1H)-one (Hnpo) ligand, novel nonhelical HMSCs [Mo₂M(npo)₄(NCS)₂] (M = Fe, Co, Ni) were synthesised and they exhibited high single-molecule conductance.

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Article information

DOI: https://doi.org/10.1039/C7CC05449A
Article type: Communication
Submitted: 14 Jul 2017
Accepted: 17 Jul 2017
First published: 17 Jul 2017

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Chem. Commun., 2017,53, 8886-8889

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Nonhelical heterometallic [Mo₂M(npo)₄(NCS)₂] string complexes (M = Fe, Co, Ni) with high single-molecule conductance

W. Chang, C. Chang, M. Sigrist, S. Hua, T. Liu, G. Lee, B. Jin, C. Chen and S. Peng, Chem. Commun., 2017, 53, 8886 DOI: 10.1039/C7CC05449A

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Chemical Communications