Electrochemical control of the switching process of photochromic dimethyldihydropyrene derivatives

A. Bakkar; F. Lafolet; M. Boggio-Pasqua; D. Jouvenot; E. Saint-Aman; S. Cobo

doi:10.1039/C7CC05223E

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Electrochemical control of the switching process of photochromic dimethyldihydropyrene derivatives†

A. Bakkar,^a F. Lafolet,

^ab M. Boggio-Pasqua,*^c D. Jouvenot,^a E. Saint-Aman^a and S. Cobo

*^a

Author affiliations

* Corresponding authors

^a Univ. Grenoble Alpes, CNRS, DCM, F-38000 Grenoble, France

^b Paris Diderot, Sorbonne Paris Cité, ITODYS, UMR 7086 CNRS, 15 rue Jean-Antoine de Baïf, 75205 Paris Cedex 13, France

^c Univ. Toulouse 3, CNRS, LCPQ UMR 5626, 118 route de Narbonne, 31062 Toulouse, France

Abstract

The electrochemical control of the isomerization process of a photo-switchable dimethyldihydropyrene (DHP) derivative has been investigated. Spectro-electrochemical experiments clearly evidence that the substitution of the DHP core by electron-withdrawing entities can be used to control the opening/closing process.

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Article information

DOI: https://doi.org/10.1039/C7CC05223E
Article type: Communication
Submitted: 06 Jul 2017
Accepted: 27 Jul 2017
First published: 28 Jul 2017

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Chem. Commun., 2017,53, 9360-9363

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Electrochemical control of the switching process of photochromic dimethyldihydropyrene derivatives

A. Bakkar, F. Lafolet, M. Boggio-Pasqua, D. Jouvenot, E. Saint-Aman and S. Cobo, Chem. Commun., 2017, 53, 9360 DOI: 10.1039/C7CC05223E

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Chemical Communications

Electrochemical control of the switching process of photochromic dimethyldihydropyrene derivatives†

Abstract

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Electrochemical control of the switching process of photochromic dimethyldihydropyrene derivatives

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