Synthesis of carbonylated heteroaromatic compounds via visible-light-driven intramolecular decarboxylative cyclization of o-alkynylated carboxylic acids

Fei Gao; Jiu-Tao Wang; Lin-Lin Liu; Na Ma; Chao Yang; Yuan Gao; Wujiong Xia

doi:10.1039/C7CC04813K

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Synthesis of carbonylated heteroaromatic compounds via visible-light-driven intramolecular decarboxylative cyclization of o-alkynylated carboxylic acids†

Fei Gao,^a Jiu-Tao Wang,^a Lin-Lin Liu,^a Na Ma,^a Chao Yang,^a Yuan Gao^b and Wujiong Xia

*^a

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* Corresponding authors

^a State Key Lab of Urban Water Resource and Environment, Harbin Institute of Technology (Shenzhen), Shenzhen, China
E-mail: xiawj@hit.edu.cn

^b School of Chemistry and Chemical Engineering, Yantai University, #30 Qingquan RD, Laishan District, Yantai, China

Abstract

An efficient strategy for the easy access to carbonylated heteroaromatic compounds has been developed via a visible-light-promoted intramolecular decarboxylative cyclization reaction of o-alkynylated carboxylic acids. This method is characterized by its benign conditions and the tolerance to a wide range of functionalities.

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Article information

DOI: https://doi.org/10.1039/C7CC04813K
Article type: Communication
Submitted: 21 Jun 2017
Accepted: 05 Jul 2017
First published: 06 Jul 2017

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Chem. Commun., 2017,53, 8533-8536

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Synthesis of carbonylated heteroaromatic compounds via visible-light-driven intramolecular decarboxylative cyclization of o-alkynylated carboxylic acids

F. Gao, J. Wang, L. Liu, N. Ma, C. Yang, Y. Gao and W. Xia, Chem. Commun., 2017, 53, 8533 DOI: 10.1039/C7CC04813K

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Chemical Communications

Synthesis of carbonylated heteroaromatic compounds via visible-light-driven intramolecular decarboxylative cyclization of o-alkynylated carboxylic acids†

Abstract

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Synthesis of carbonylated heteroaromatic compounds via visible-light-driven intramolecular decarboxylative cyclization of o-alkynylated carboxylic acids

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