Issue 65, 2017
From the journal:

Chemical Communications

A green route to methyl acrylate and acrylic acid by an aldol condensation reaction over H-ZSM-35 zeolite catalysts†

Zhanling Ma,abc   Xiangang Ma,a   Hongchao Liu,a   Yanli He,a   Wenliang Zhu,*a   Xinwen Guo ORCID logo b  and  Zhongmin Liu ORCID logo *a  

* Corresponding authors

a National Engineering Laboratory for Methanol to Olefins, Dalian National Laboratory for Clean Energy, iChEM, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P. R. China
E-mail: wlzhu@dicp.ac.cn, liuzm@dicp.ac.cn

b State Key Laboratory of Fine Chemicals, PSU-DUT Joint Center for Energy Research, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, P. R. China

c University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Abstract

A one-step aldol condensation reaction to produce MA and AA is a green and promising strategy. Here, the aldol condensation reaction was first conducted with DMM and MAc over different types of zeolite catalysts. The H-ZSM-35 zeolite demonstrates excellent catalytic performance with a DMM conversion of 100% and a MA + AA selectivity of up to 86.2% and superior regeneration ability, with great potential for industrial operation.

Graphical abstract: A green route to methyl acrylate and acrylic acid by an aldol condensation reaction over H-ZSM-35 zeolite catalysts

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Article information

DOI
https://doi.org/10.1039/C7CC04574C
Article type
Communication
Submitted
13 Jun 2017
Accepted
20 Jul 2017
First published
20 Jul 2017

Chem. Commun., 2017,53, 9071-9074

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A green route to methyl acrylate and acrylic acid by an aldol condensation reaction over H-ZSM-35 zeolite catalysts

Z. Ma, X. Ma, H. Liu, Y. He, W. Zhu, X. Guo and Z. Liu, Chem. Commun., 2017, 53, 9071 DOI: 10.1039/C7CC04574C

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