Issue 61, 2017

Transforming a chemically labile [2+3] imine cage into a robust carbamate cage

Abstract

The synthesis of a highly acid and base-stable shape-persistent porous carbamate cage is presented. This cage is stable even in hot (100 °C) 1 M hydrochloric acid (pH = 0) or in concentrated hydrochloric acid (pH = −1) at room temperature without decomposition.

Graphical abstract: Transforming a chemically labile [2+3] imine cage into a robust carbamate cage

Supplementary files

Article information

Article type
Communication
Submitted
12 May 2017
Accepted
07 Jul 2017
First published
07 Jul 2017

Chem. Commun., 2017,53, 8616-8619

Transforming a chemically labile [2+3] imine cage into a robust carbamate cage

X. Hu, W. Zhang, F. Rominger, I. Wacker, R. R. Schröder and M. Mastalerz, Chem. Commun., 2017, 53, 8616 DOI: 10.1039/C7CC03677A

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