The fusion of two homoleptic complexes quantitatively created a novel three-component nanorotor. The intra-supramolecular rotational dynamics leads to a rapid exchange (k298 = 24.0 ± 2.5 kHz) of two degenerate Npy → ZnPor interactions. Metal exchange at the remote HETTAP complexation site provided a faster nanorotor (k298 = 34.0 ± 3.0 kHz).
A. Goswami, I. Paul and M. Schmittel, Chem. Commun., 2017, 53, 5186 DOI: 10.1039/C7CC01977G
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