Issue 34, 2017
From the journal:

Chemical Communications

A ligand design with a modified naphthyridylamide for achieving the longest EMACs: the 1st single-molecule conductance of an undeca-nickel metal string†

Po-Jung Chen,a   Marc Sigrist,b   Er-Chien Horng,a   Geng-Min Lin,a   Gene-Hsiang Lee,a   Chun-hsien Chen ORCID logo *a  and  Shie-Ming Peng*ab  

* Corresponding authors

a Department of Chemistry and Centre for Emerging Material and Advanced Devices, National Taiwan University, Taipei 106, Taiwan
E-mail: smpeng@ntu.edu.tw, chhchen@ntu.edu.tw
Fax: +886-2-83693765

b Institute of Chemistry, Academia Sinica, Taipei 115, Taiwan

Abstract

Striding to extend the length of metal-atom strings, oligo-α-pyridylamino ligands are modulated with naphthyridyl moieties leading to the undeca-nickel mixed-valence complexes [Ni11(bnatpya)4Cl2]4+ (1) and [Ni11(bnatpya)4Cl2]2+ (2). The first single-molecule conductance measurements of a linear undeca-nickel chain were performed.

Graphical abstract: A ligand design with a modified naphthyridylamide for achieving the longest EMACs: the 1st single-molecule conductance of an undeca-nickel metal string

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C7CC01831B
Article type
Communication
Submitted
10 Mar 2017
Accepted
24 Mar 2017
First published
31 Mar 2017

Chem. Commun., 2017,53, 4673-4676

Permissions

Request permissions

A ligand design with a modified naphthyridylamide for achieving the longest EMACs: the 1st single-molecule conductance of an undeca-nickel metal string

P. Chen, M. Sigrist, E. Horng, G. Lin, G. Lee, C. Chen and S. Peng, Chem. Commun., 2017, 53, 4673 DOI: 10.1039/C7CC01831B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements