Azomethine-isocyanide [3+2] cycloaddition to imidazoles promoted by silver and DBU

Xiaoshan Huang; Xuefeng Cong; Pengbing Mi; Xihe Bi

doi:10.1039/C7CC00772H

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Azomethine-isocyanide [3+2] cycloaddition to imidazoles promoted by silver and DBU†

Xiaoshan Huang,^a Xuefeng Cong,^a Pengbing Mi^a and Xihe Bi

*^ab

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* Corresponding authors

^a Jilin Province Key Laboratory of Organic Functional Molecular Design & Synthesis, Department of Chemistry, Northeast Normal University, 5268 Renmin Street, 130024 Changchun, China
E-mail: bixh507@nenu.edu.cn

^b State Key Laboratory of Elemento-Organic Chemistry, Nankai University, 300071 Tianjin, China

Abstract

A new silver-promoted [3+2] cycloaddition of azomethine ylides with isocyanides has been described. The methodology provides an efficient and modular approach to 1,2,4-trisubstituted imidazoles of vital bioactive molecules and atypical antipsychotics analogues.

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Article information

DOI: https://doi.org/10.1039/C7CC00772H
Article type: Communication
Submitted: 28 Jan 2017
Accepted: 09 Mar 2017
First published: 13 Mar 2017

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Chem. Commun., 2017,53, 3858-3861

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Azomethine-isocyanide [3+2] cycloaddition to imidazoles promoted by silver and DBU

X. Huang, X. Cong, P. Mi and X. Bi, Chem. Commun., 2017, 53, 3858 DOI: 10.1039/C7CC00772H

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Chemical Communications

Azomethine-isocyanide [3+2] cycloaddition to imidazoles promoted by silver and DBU†

Abstract

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Azomethine-isocyanide [3+2] cycloaddition to imidazoles promoted by silver and DBU

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