Issue 1, 2017

Convenient route to tetraarylphosphonium polyelectrolytes via metal-catalysed P–C coupling polymerisation of aryl dihalides and diphenylphosphine

Abstract

A P–C bond-forming reaction has been applied to the convenient preparation of tetraarylphosphonium polyelectrolytes (TPELs) from aryl dihalides and diphenylphosphine. A TPEL having a thermal decomposition temperature of 460 °C that is also stable to heating at 65 °C in 6 M NaOH(aq) for at least 24 h has been prepared by this method.

Graphical abstract: Convenient route to tetraarylphosphonium polyelectrolytes via metal-catalysed P–C coupling polymerisation of aryl dihalides and diphenylphosphine

Supplementary files

Article information

Article type
Communication
Submitted
08 Nov 2016
Accepted
21 Nov 2016
First published
08 Dec 2016

Chem. Commun., 2017,53, 252-254

Convenient route to tetraarylphosphonium polyelectrolytes via metal-catalysed P–C coupling polymerisation of aryl dihalides and diphenylphosphine

W. Wan, X. Yang and R. C. Smith, Chem. Commun., 2017, 53, 252 DOI: 10.1039/C6CC08938K

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