Ar–P bond construction by the Pd-catalyzed oxidative cross-coupling of arylsilanes with H-phosphonates via C–Si bond cleavage

Haiqing Luo; Haidong Liu; Xingwei Chen; Keke Wang; Xuzhong Luo; Kejun Wang

doi:10.1039/C6CC08408G

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Ar–P bond construction by the Pd-catalyzed oxidative cross-coupling of arylsilanes with H-phosphonates via C–Si bond cleavage†

Haiqing Luo,

*^a Haidong Liu,^a Xingwei Chen,^a Keke Wang,^a Xuzhong Luo^a and Kejun Wang*^a

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* Corresponding authors

^a Department of Chemistry & Chemical Engineering, Gannan Normal University, Ganzhou 341000, China
E-mail: luohq@gnnu.cn, wangkejun@sina.com

Abstract

A novel and efficient methodology that allows for the construction of Ar–P bonds via the Pd-catalyzed oxidative cross-coupling reaction of various arylsilanes with H-phosphonates leading to valuable arylphosphonates has been developed.

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Article information

DOI: https://doi.org/10.1039/C6CC08408G
Article type: Communication
Submitted: 19 Oct 2016
Accepted: 16 Dec 2016
First published: 19 Dec 2016

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Chem. Commun., 2017,53, 956-958

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Ar–P bond construction by the Pd-catalyzed oxidative cross-coupling of arylsilanes with H-phosphonates via C–Si bond cleavage

H. Luo, H. Liu, X. Chen, K. Wang, X. Luo and K. Wang, Chem. Commun., 2017, 53, 956 DOI: 10.1039/C6CC08408G

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Chemical Communications

Ar–P bond construction by the Pd-catalyzed oxidative cross-coupling of arylsilanes with H-phosphonates via C–Si bond cleavage†

Abstract

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Ar–P bond construction by the Pd-catalyzed oxidative cross-coupling of arylsilanes with H-phosphonates via C–Si bond cleavage

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